2010～現在
伊藤大道 高分子微粒子の合成法と構造・形状の制御および評価方法 (Preparation, Structure, Shape, and Characterization of Polymer Microspheres) |
Hiroaki Shimomoto, Takumi Kubo, Kazunari Nishigawa, Hazuki Okuda, Makoto Ishimoto, Tomomichi Itoh, Eiji Ihara Synthesis of dendronized polymers through Pd-initiated C1 polymerization of diazoacetates with different generation ester-type dendron groups |
Ihara, Eiji Development of polymer syntheses using diazocarbonyl compounds as monomers Polym. J., 2025, 57, 1–23[selected as the cover image of this issue]
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井原栄治・下元浩晃 C1重合によるC（sp3）主鎖高分子の合成法 |
伊藤大道 光応答性架橋アゾベンゼン高分子微粒子の開発（Development of photoresponsive crosslinked azobenzene polymer particles） |
Kawakami, Chikara; Hara, Mitsuo; Nagano, Shusaku; Shimomoto, Hiroaki; Yorimoto, Yoshitaka; Yamada, Tomohiro; Oda, Shuichiro; Ihara, Eiji; Seki,Takahiro Assembly Structure Formation in Bulk and Ultrathin Films of Poly(substituted methylene) Having an Azobenzene Side Chain |
Shimomoto, Hiroaki; Izumoto, Takaya; Yamashita, Kazuki; Itoh, Tomomichi; Ihara, Eiji A salicylaldiminate/Pd(trifluoroacetate)2 [SalAld/Pd(tfa)2] initiating system for C1 polymerization of diazoacetate: generation of an active initiator from ordinary reagents with facile procedures |
Shimomoto, Hiroaki; Inouchi, Shota; Itoh, Tomomichi; Ihara, Eiji Postpolymerization modification of poly(2-alkoxyethoxycarbonylmethylene)s: efficient formation and reactivity of ketene silyl acetal repeating unit in the polymer main chain |
Shimomoto, Hiroaki; Katashima, Itsuki; Murakami, Hirokazu; Itoh, Tomomichi; Ihara, Eiji Effect of the Alkyl Side-Chain Structure on Melting Point of Atactic Poly(alkoxycarbonylmethylene)s: Incorporation of Amide-Linkage Leading to Polymers with High Melting Point Macromolecules, 2023, 56, 4639–4648 関連記事 |
Itoh, Tomomichi; Kimoto, Moeka; Kuroda, Natsumi; Ishizaki, Keisuke; Yukihiro, Eiji; Shimomoto, Hiroaki; Ihara, Eiji Light-Responsive Crosslinked Polymer Particles from Heterogeneous Polymerization of an Asymmetric Divinyl Azobenzene Monomer |
Shimomoto, H.; Miyano, Y.; Kinoshita, K.; Itoh, T.; Ihara, E. Initiating Ability of Diphosphine- and Diamine-ligated Pd Complexes/NaBPh4 Systems for C1 Polymerization of Diazoacetates |
Wang, Y.; Shao, Y.; Liou, G.; Nagao, S.; Makino, Y.; Akiyama, E.; Kato, M.; Shimomoto, H.; Ihara, E. Synthesis and electrochromic properties of polyamines containing a 4,4′-diaminotriphenylamine-N,N′-diyl unit in the polymer backbone: Ru-catalyzed N–H insertion polycondensation of 1,4-phenylenebis(diazoacetate) with 4,4′-diaminotriphenylamine derivatives |
Itoh, T.; Okuno, M.; Moriya, Y.; Shimomoto, H.; Ihara E. Poly(acrylic acid) block copolymers as stabilizers for dispersion polymerization |
Shimomoto, H.; Hayashi, H.; Aramasu, K.; Itoh, T.; Ihara, E. Polymerization of Diazoacetates Initiated by the Pd(N-arylmaleimide)/NaBPh4 System: Maleimide Insertion into a Pd–C Bond Preceding to Initiation Leading to Efficient α-Chain-End Functionalization of Poly(alkoxycarbonylmethylene)s |
伊藤大道 専門的文章作成能力の涵養を図る実践的演習と追跡評価システムの構築（Practical Training for Writing Papers in Specific Fields and Construction of a Tracking and Evaluation System） |
Shimomoto, H.; Tsunematsu, S.; Itoh, T.; Ihara, E. Reactivity of Poly(alkoxycarbonylmethylene)s under Basic Conditions: Alkylation of Main Chain Carbon Atoms via Ketene Silyl Acetal-type Intermediate and Cleavage of Carbon–carbon Main Chain |
Shimomoto, H.; Hosaki, R.; Hiramatsu, D.; Itoh, T.; Ihara, E. Pd-Initiated Polymerization of Dendron-Containing Diazoacetates to Afford Dendronized Poly(substituted methylene)s with Narrow Molecular Weight Distribution and Its Application to Synthesis of pH-Responsive Dendronized Polymers Macromolecules, 2020, 53, 6369–6379; announced at a press conference by Ehime University |
Itoh, T.; Tamamitsu, T.; Aki, T.; Tsutsui, K.; Mori, Y.; Kudo, H.; Tokita, M.; Shimomoto, H.; Ihara, E. Nonspherical Uniaxial Azobenzene Polymer Particles and Their Shape Changes under UV- or White-Light Irradiation for Stimuli-Response Applications |
Shimomoto, H.; Moriya, T.; Mori, T.; Itoh, T.; Kanehashi, S.; Ihara, E. Single-Component Polycondensation of Bis(alkoxycarbonyldiazomethyl)aromatic Compounds To Afford Poly(arylene vinylene)s with an Alkoxycarbonyl Group on Each Vinylene Carbon Atom |
Shimomoto, H.; Nakajima, M.; Watanabe, A.; Murakami, M.; Itoh, T.; Ihara, E. Effects of Solvent, Additive, and π-Allyl Ligand Structure on the Polymerization Behavior of Diazoacetates Initiated by π-AllylPd Complexes Polym. Chem., 2020, 11, 1774–1784 [selected as one of Polymer Chemistry Emerging Investigators] |
Shimomoto, H. Synthesis of functional polymers by the Pd-mediated polymerization of diazoacetates and polycondensation of bis(diazocarbonyl) compounds Polym. J., 2020, 52, 269–277 [selected as one of featured articles of this issue] |
Shimomoto, H.; Yamada, T.; Itoh, T.; Ihara, E. Carbon-carbon Main Chain Polymer with Accumulated Oligo(ethylene glycol)-substituted Cyclotriphosphazenes: Study on LCST-type Phase Separation of Organic-inorganic Poly(substituted methylene)s |
Shimomoto, H.; Ichihara, S.; Hayashi, H.; Itoh, T.; Ihara, E. Polymerization of alkyl diazoacetates initiated by Pd(naphthoquinone)/borate systems: dual role of naphthoquinones as oxidant and anionic ligand for generating active Pd(II) species |
Shimomoto, H.; Mori, T.; Itoh, T.; Ihara, E. Poly(Β-keto enol ether) Prepared by Three-Component Polycondensation of Bis(diazoketone), Bis(1,3-diketone), and Tetrahydrofuran: Mild Acid-Degradable Polymers To Afford Well-Defined Low Molecular Weight Components |
Ihara, E.; Shimomoto, H. Polymerization of Diazoacetates: New Synthetic Strategy for C-C Main Chain Polymers |
Itoh, T.; Kojima, K.; Shimomoto, H.; Ihara, E. Control of lengths and densities of surface-attached chains on polymer particles prepared by dispersion polymerization using macromonomer stabilizer |
Takaya, T.; Oda, T.; Shibazaki, Y.; Hayashi, Y.; Shimomoto, H.; Ihara, E.; Ishibashi, Y.; Asahi, T.; Iwata, K. Excited-State Dynamics of Pyrene Incorporated into Poly(substituted methylene)s: Effects of Dense Packing of Pyrenes on Excimer Formation |
Shikinaka, K; Suzuki, K.; Masunaga, H.; Ihara, E.; Shigehara, K. Stiff- & hierarchical-chain nature of atactic and stereoregular poly(substituted methylene)s |
Shimomoto. H; Kudo, T.; Tsunematsu, S; Itoh, T.; Ihara, H. Fluorinated Poly(substituted methylene)s Prepared by Pd-Initiated Polymerization of Fluorine-Containing Alkyl and Phenyl Diazoacetates: Their Unique Solubility and Postpolymerization Modification |
Kato, F.; Chandra, A.; Tokita, M.; Asano, H.; Shimomoto, H.; Ihara, E.; Hayakawa, T. Self-Assembly of Hierarchical Structures Using Cyclotriphosphazene-Containing Poly(substituted methylene) Block Copolymers |
Shimomoto, H.; Mukai, H.; Bekku, H.; Itoh, T.; Ihara, E. Ru-catalyzed Polycondensation of Dialkyl 1,4-Phenylene-bis(diazoacetate) with Dianiline: Synthesis of Well-defined Aromatic Polyamines Bearing Alkoxycarbonyl Group at Adjacent Carbon of Each Nitrogen in the Main Chain Framework |
伊藤大道 表面構造を制御した刺激応答性高分子微粒子の一段合成 |
Itoh, T. Liquid Crystalline Materials in Mesoscopic Scale In Conjugated Objects – Developments, Synthesis, and Applications; Nagai, A., Takagi, K., Eds.; Pan Stanford Publishing Pte. Ltd.: Singapore, 2017; pp.253–281 |
Shimomoto, H.; Kawamata, J.; Murakami, H.; Yamashita, K.; Itoh, T.; Ihara, E. Polymerization of Alkyl Diazoacetates Initiated with Amidinate/Pd System: Efficient Synthesis of High Molecular Weight Poly(alkoxycarbonylmethylene)s with Moderate Stereoregularity |
Itoh, T.; Okada, S.; Kojima, K.; Asano, H.; Shimomoto, H.; Ihara, E. Controlled cationic polymer particles prepared by dispersion polymerizations with poly(L-lysine) macromonomers as a stabilizer |
井原栄治・下元浩晃 ジアゾ酢酸エステルの重合によるポリ（置換メチレン）合成 |
下元浩晃・井原栄治 Pd錯体を開始剤とするジアゾ酢酸エステルの重合の新展開 |
Shimomoto, H.; Kikuchi, M.; Aoyama, J.; Sakayoshi, D.; Itoh, T.; Ihara, E. Cyclopolymerization of Bis(diazocarbonyl) Compounds Leading to Well-defined Polymers Essentially Consisting of Cyclic Constitutional Units |
Shimomoto, H.; Uegaito, T.; Yabuki, S.; Teratani, S; Itoh, T.; Ihara, E.; Hoashikawa, N.; Koiwai, A.; Hasegawa, N. Lithium ion conductivity of polymers containing N-phenyl-2,6-dimethoxybenzamide framework in their side chains: possible role of bond rotation in polymer side chain substituents for efficient ion transport |
Shimomoto, H.; Oda, A.; Kanayama, M.; Sako, T.; Itoh, T.; Ihara, E.; Hoashikawa, N.; Koiwai, A.; Hasegawa, N. Pd-initiated Polymerization of Diazo Compounds Bearing Dialkoxyphosphinyl Group and Hydrolysis of the Resulting Polymers and Oligomers to Afford Phosphonic Acid-Containing Products |
Shimomoto, H.; Shimizu, K.; Takeda, C.; Kikuchi, M.; Kudo, T.; Mukai, H.; Itoh, T.; Ihara, E.; Hoshikawa, N.; Koiwai, A.; Hasegawa, N. Synthesis of Polymers with Densely-grafted Oligo(ethylene glycol)s by Pd-initiated Polymerization of Oxyethylene-containing Diazoacetates |
井原栄治; 伊藤大道; 下元浩晃 Pd錯体を開始剤とするジアゾカルボニル化合物の重合 |
Itoh, T.; Tamamitsu, T.; Shimomoto, H.; Ihara, E. Surface Structure and Composition of Narrowly-Distributed Functional Polystyrene Particles Prepared by Dispersion Polymerization with Poly(L-glutamic acid) Macromonomer as Stabilizer |
Shimomoto, H.; Asano, H.; Itoh, T.; Ihara, E. Pd-initiated Controlled Polymerization of Diazoacetates with a Bulky Substituent: Synthesis of Well-defined Homopolymers and Block Copolymers with Narrow Molecular Weight Distribution from Cyclophosphazene-containing Diazoacetates |
Ihara, E.; Itoh, T.; Shimomoto, H. Polymerization of Alkyl Diazoacetates Initiated with Pd Complexes |
Shimomoto, H.; Itoh, E.; Itoh, T.; Ihara, E.; Hoshikawa, N.; Hasegawa, N. Polymerization of Hydroxy-Containing Diazoacetates: Synthesis of Hydroxy-Containing “Poly(substituted Methylene)s” by Palladium-Mediated Polymerization and Poly(ester–ether)s by Polycondensation through O–H Insertion Reaction |
Itoh, T.; Abe, I.; Tamamitsu, T.; Shimomoto, H.; Inoue, K.; Ihara,E. Surface Structure of Stimuli-Responsive Polystyrene Particles Prepared by Dispersion Polymerization with a Polystyrene/poly(L-Lysine) Block Copolymer as a Stabilizer |
Shimomoto, H.; Hara, Y.; Itoh, T.; Ihara, E. Synthesis of Well-Defined Unsaturated Polyesters by Transition-Metal-Catalyzed Polycondensation of Bis(diazoacetate)s |
| Ihara, E.; Ishii, S.; Yokoyama, K.; Fujiwara, Y.; Ueda, T.; Inoue, K.; Itoh, T.; Momose, H.; Nodono, M. Synthesis of Polymers with a Norbornane Backbone by Radical Copolymerization of Alkyl 2-Norbornene-2-Carboxylates for Photoresist Applications [selected as one of featured articles of this issue] |
Ihara, E.; Ueda, T.; Yokoyama, K.; Fujiwara, Y.; Inoue, K.; Itoh, T.; Shimomoto, H.; Momose, H.; Nodono, M. Radical Copolymerization of Alkyl Cyclobutenecarboxylates Fused with Cycloaliphatic Framework with Alkyl (meth)acrylates |
Ihara, E.; Okada, R.; Sogai, T.; Asano, T.; Kida, M.; Inoue, K.; Itoh, T.; Shimomoto, H.; Ishibashi, Y.; Asahi, T. Pd-Mediated Polymerization of Diazoacetates with Aromatic Ester Group: Synthesis and Photophysical Property of poly(1-Pyrenylmethoxycarbonylmethylene) |
Itoh, T.; Komada, S.; Ihara, E.; Inoue, K. Dispersion Polymerization of Styrene Using a Polystyrene/Poly(L-Glutamic Acid) Block Copolymer as a Stabilizer |
Itoh, T.; Hatanaka, T.; Ihara, E.; Inoue, K. Helix–coil Transformation of Poly(γ-Benzyl-L-Glutamate) with Polystyrene Attached to the N or C Terminus in Trifluoroacetic Acid–chloroform Mixtures [selected as one of featured articles of this issue] |
Ihara, E.; Akazawa, M.; Itoh, T.; Fujii, M.; Yamashita, K.; Inoue, K.; Itoh, T.; Shimomoto, H. Π-AllylPdCl-Based Initiating Systems for Polymerization of Alkyl Diazoacetates: Initiation and Termination Mechanism Based on Analysis of Polymer Chain End Structures |
Shimomoto, H.; Kanaoka, S.; Aoshima S. Precise Synthesis of End-Functionalized Thermosensitive Poly(vinyl ether)s by Living Cationic Polymerization |
Shimomoto H.; Yoshida H.; Kanaoka S.; Aoshima S. Synthesis of Graft Copolymers Based on Selective Living Cationic Polymerization Using an Acetal Group with a Combination of Lewis Acids |
Shimomoto H.; Fukami D.; Irita T.; Katsukawa K.; Nagai T.; Kanaoka S.; Aoshima S. Synthesis of Fluorine-Containing Star-Shaped Poly(vinyl ether)s via Arm-Linking Reactions in Living Cationic Polymerization |
Tsuboi Y.; Kikuchi K.; Kitamura N.; Shimomoto H.; Kanaoka S.; Aoshima S. Phase Separation Dynamics of Aqueous Poly[(2-ethoxy) ethoxy ethyl vinyl ether] Solutions as Explored using the Laser T-Jump Technique Combined With Photometry |
井原栄治 遷移金属錯体を開始剤とするジアゾ酢酸エステルの重合 未来材料 2011, 7, 18-24 |
Ihara, E.; Hara, Y.; Itoh, T.; Inoue, K. Three-Component Polycondensation of Bis(diazoketone) with Dicarboxylic Acids and Cyclic Ethers: Synthesis of New Types of Poly(ester Ether Ketone)s [Highlighted inSynfacts, 2011, 1069] |
Ihara, E.; Nishida, H.; Fujii, M.; Itoh, T.; Inoue, K. Thermally Induced Polymerization and Copolymerization with Styrene of Diazoketones in the Presence of Benzoquinone |
Ihara, E.; Takahashi, H.; Akazawa, M.; Itoh, T.; Inoue, K. Polymerization of Various Alkyl Diazoacetates Initiated with (N-Heterocyclic Carbene)Pd/Borate Systems |
Shimomoto H.; Fukami D.; Kanaoka S.; Aoshima S. Fluorinated Vinyl Ether Homopolymers and Copolymers: Living Cationic Polymerization and Temperature-Induced Solubility Transitions in Various Organic Solvents Including Perfluoro Solvents |
Shimomoto H.; Fukami D.; Kanaoka S.; Aoshima S. Fluorine-Containing Vinyl Ether Polymers: Living Cationic Polymerization in Fluorinated Solvents as New Media and Unique Solubility Characteristics in Organic Solvents |
Kono K.; Nakashima S.; Kokuryo D.; Aoki I.; Shimomoto H.; Aoshima S.; Maruyama K.; Yuba E.; Kojima C.; Harada A.; Ishizaki Y. Multi-Functional Liposomes Having Temperature-Triggered Release and Magnetic Resonance Imaging for Tumor-Specific Chemotherapy |
井原栄治 ポリ（置換メチレン）合成：炭素―炭素結合を主鎖骨格とする高分子の新しい合成法 触媒 2010, 52, 575-581 |
井原栄治 １炭素ユニットから主鎖を構築する高分子合成法 化学と教育 2010, 58, 520-521 |
井原栄治 遷移金属錯体を開始剤とするジアゾ酢酸エステルの重合 高分子 2010, 59, 790-791 |
Ihara, E. Poly(substituted methylene) Synthesis: Construction of C-C Main Chain from One Carbon Unit |
Ihara, E.; Yagi, Y.; Kurokawa, A.; Itoh, T.; Inoue, K. Preparation of Poly[(vinyl Alcohol)-co-(methyl Methacrylate)] by Oxidative Transformation of C–Si Bond in Poly[di(isobutoxy)phenylvinylsilane-co-(methyl Methacrylate)] |
Ihara, E.; Honjyo, S.; Kobayashi, K.; Ishii, S.; Itoh, T.; Inoue, K.; Momose, H.; Nodono, M. Radical Copolymerization of Methyl 2-Norbornene-2-Carboxylate and 2-Phenyl-2-Norbornene with Styrene, Alkyl Acrylate, and Methyl Methacrylate: Facile Incorporation of Norbornane Framework into Polymer Main Chain and Its Effect on Glass Transition Temperat |
Ihara, E.; Saiki, K.; Goto, Y.; Itoh, T.; Inoue, K. Polycondensation of Bis(diazocarbonyl) Compounds with Aromatic Diols and Cyclic Ethers: Synthesis of New Type of Polyetherketones |